Recent Progress in the Development of Anode Materials for Solid Oxide Fuel Cells

被引:330
作者
Cowin, Peter I. [1 ]
Petit, Christophe T. G. [1 ]
Lan, Rong [1 ]
Irvine, John T. S. [2 ]
Tao, Shanwen [1 ]
机构
[1] Univ Strathclyde, Dept Chem & Proc Engn, Glasgow G1 1XJ, Lanark, Scotland
[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
基金
英国工程与自然科学研究理事会;
关键词
DOPED STRONTIUM-TITANATE; SULFUR-TOLERANT ANODE; BRONZE TYPE PHASES; A-SITE DEFICIENCY; ELECTRICAL-PROPERTIES; SOFC ANODES; COAL SYNGAS; PEROVSKITE ANODE; REDOX STABILITY; CERMET ANODES;
D O I
10.1002/aenm.201100108
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The field of research into solid oxide fuel cell (SOFC) anode materials has been rapidly moving forward. In the four years since the last in-depth review significant advancements have been made in the reduction of the operating temperature and improvement of the performance of SOFCs. This progress report examines the developments in the field and looks to draw conclusions and inspiration from this research. A brief introduction is given to the field, followed by an overview of the principal previous materials. A detailed analysis of the developments of the last 4 years is given using a selection of the available literature, concentrating on metal-fluorite cermets and perovskite-based materials. This is followed by a consideration of alternate fuels for use in SOFCs and their associated problems and a short discussion on the effect of synthesis method on anode performance. The concluding remarks compile the significant developments in the field along with a consideration of the promise of future research. The recent progress in the development of anode materials for SOFCs based on oxygen ion conducting electrolytes is reviewed.
引用
收藏
页码:314 / 332
页数:19
相关论文
共 227 条
[1]   Structure, thermal stability and electrical properties of Ca(V0.5Mo0.5)O3 as solid oxide fuel cell anode [J].
Aguadero, A. ;
de la Calle, C. ;
Alonso, J. A. ;
Perez-Coll, D. ;
Escudero, M. J. ;
Daza, L. .
JOURNAL OF POWER SOURCES, 2009, 192 (01) :78-83
[2]   The effect of porosity gradient in a Nickel/Yttria Stabilized Zirconia anode for an anode-supported planar solid oxide fuel cell [J].
An, Chung Min ;
Song, Jung-Hoon ;
Kang, Inyong ;
Sammes, Nigel .
JOURNAL OF POWER SOURCES, 2010, 195 (03) :821-824
[3]   Improvement of Ni/SDC anode by alkaline earth metal oxide addition for direct methane-solid oxide fuel cells [J].
Asamoto, Makiko ;
Miyake, Shinji ;
Sugihara, Kazunari ;
Yahiro, Hidenori .
ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (07) :1508-1511
[4]   Advanced anodes for high-temperature fuel cells [J].
Atkinson, A ;
Barnett, S ;
Gorte, RJ ;
Irvine, JTS ;
Mcevoy, AJ ;
Mogensen, M ;
Singhal, SC ;
Vohs, J .
NATURE MATERIALS, 2004, 3 (01) :17-27
[5]  
AURIVILLIUS B, 1950, ARK KEMI, V1, P463
[6]   ELECTRICAL-CONDUCTIVITY IN STRONTIUM-TITANATE [J].
BALACHANDRAN, U ;
EROR, NG .
JOURNAL OF SOLID STATE CHEMISTRY, 1981, 39 (03) :351-359
[7]   A new anode material for intermediate solid oxide fuel cells [J].
Bao, Weitao ;
Guan, Hangmin ;
Cheng, Jihai .
JOURNAL OF POWER SOURCES, 2008, 175 (01) :232-237
[8]   A symmetrical solid oxide fuel cell demonstrating redox stable perovskite electrodes [J].
Bastidas, DM ;
Tao, SW ;
Irvine, JTS .
JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (17) :1603-1605
[9]  
Baur E, 1937, Z ELKTROCHEM ANGEW P, V43, P727
[10]   Development and characterisation of (Ni, Cu, Co)-YSZ and Cu-Co-YSZ cermets anode materials for SOFC application [J].
Benyoucef, Amel ;
Klein, Didier ;
Coddet, Christian ;
Benyoucef, Boumediene .
SURFACE & COATINGS TECHNOLOGY, 2008, 202 (10) :2202-2207