Preparation of positive LiCoO2 films by electron cyclotron resonance (ECR) plasma sputtering method and its application to all-solid-state thin-film lithium batteries

被引:31
作者
Hayashi, Masahiko [1 ]
Takahashi, Masaya [1 ]
Sakurai, Yoji [2 ]
机构
[1] NTT Corp, NTT Energy & Environm Syst Labs, Kanagawa 2430198, Japan
[2] NTT Corp, NTT Microsyst Integrat Labs, Kanagawa 2430198, Japan
关键词
LiCoO2; electron cyclotron resonance (ECR) plasma sputtering; all-solid-state thin-film battery; high energy density;
D O I
10.1016/j.jpowsour.2007.06.081
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thin films of LiCoO2 prepared by the electron cyclotron resonance (ECR) sputtering method are investigated under various deposition conditions. Well-crystallized LiCoO2 films were obtained without a post-annealing process in a high microwave and RF power range with a low O-2 to Ar ratio. All-solid-state thin-film lithium batteries using the LiCoO2 films (thickness: 6.2 mu m) provided a discharge capacity of about 250 mu Ah cm(-2) with good cyclability. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:990 / 995
页数:6
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