Patterning and photolumine scent properties of perovskite-type organic/inorganic hybrid luminescent films by soft lithography

被引:50
作者
Cheng, ZY
Wang, Z
Xing, RB
Han, YC [1 ]
Lin, J
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/S0009-2614(03)01017-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Perovskite-type organic/inorganic hybrid layered compound (C6H5C2H4NH3)(2)PbI4 was synthesized. The patterning Of (C6H5C2H4NH3)(2)PbI4 thin films on silicon substrate was realized by the micromolding in capillaries (MIMIC) process, a kind of soft lithography. Bright green luminescent stripes with different widths (50, 15, 0.8 mum) have been obtained. The structure and optical properties Of (C6H5C2H4NH3)(2)PbI4 films were characterized by X-ray diffraction (XRD), UV/Vis absorption and photoluminescence excitation and emission spectra, respectively. It is shown that the organic-inorganic layered (C6H5C2H4NH3)(2)PbI4 film was c-axis oriented, paralleling to the substrate plane. Green exciton emission at 525 nm was observed in the film, and the explanations for it were given. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:481 / 486
页数:6
相关论文
共 27 条
  • [1] [Anonymous], HDB THICK FILM TECHN
  • [2] PREPARATION AND CHARACTERIZATION OF LAYERED LEAD HALIDE COMPOUNDS
    CALABRESE, J
    JONES, NL
    HARLOW, RL
    HERRON, N
    THORN, DL
    WANG, Y
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (06) : 2328 - 2330
  • [3] ORGANIC-INORGANIC HETEROSTRUCTURE ELECTROLUMINESCENT DEVICE USING A LAYERED PEROVSKITE SEMICONDUCTOR (C6H5C2H4NH3)2PBL4
    ERA, M
    MORIMOTO, S
    TSUTSUI, T
    SAITO, S
    [J]. APPLIED PHYSICS LETTERS, 1994, 65 (06) : 676 - 678
  • [4] Ultrafast photoluminescence from (C6H5C2H4NH3)2PbI4
    Fujita, T
    Nakashima, H
    Hirasawa, M
    Ishihara, T
    [J]. JOURNAL OF LUMINESCENCE, 2000, 87-9 : 847 - 849
  • [5] HARBEKE G, 1972, P INT C PHYS SEMICON, P163
  • [6] DIELECTRIC CONFINEMENT EFFECT ON EXCITONS IN PBI4-BASED LAYERED SEMICONDUCTORS
    HONG, X
    ISHIHARA, T
    NURMIKKO, AV
    [J]. PHYSICAL REVIEW B, 1992, 45 (12): : 6961 - 6964
  • [7] DIELECTRIC CONFINEMENT EFFECT FOR EXCITON AND BIEXCITON STATES IN PBI4-BASED 2-DIMENSIONAL SEMICONDUCTOR STRUCTURES
    ISHIHARA, T
    HONG, X
    DING, J
    NURMIKKO, AV
    [J]. SURFACE SCIENCE, 1992, 267 (1-3) : 323 - 326
  • [8] OPTICAL-PROPERTIES OF PBI-BASED PEROVSKITE STRUCTURES
    ISHIHARA, T
    [J]. JOURNAL OF LUMINESCENCE, 1994, 60-1 : 269 - 274
  • [9] Ishihara T., 1995, OPTICAL PROPERTIES L, P288, DOI [DOI 10.1142/9789814261388_0006, 10.1142/9789814261388_0006]
  • [10] High resolution phosphor screening method for full-color field emission display applications
    Jang, JE
    Gwak, JH
    Jin, YW
    Lee, SJ
    Park, SH
    Jung, JE
    Lee, NS
    Kim, JM
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2000, 18 (02): : 1106 - 1110