Application of EXAFS to molten salts and ionic liquid technology

被引:65
作者
Hardacre, C [1 ]
机构
[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland
[2] Queens Univ Belfast, CenTACat, Belfast BT9 5AG, Antrim, North Ireland
关键词
RTIL; structure; speciation; XAFS; absorption; X ray;
D O I
10.1146/annurev.matsci.35.100303.121832
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This paper describes the use of extended X-ray absorption fine structure spectroscopy (EXAFS) to examine the structure of molten salts and ionic liquids and species dissolved in them. The EXAFS theory is briefly described as are the methods by which EXAFS of these systems can be studied. A range of applications have used EXAFS to investigate the structure of metallic species in ionic liquids from extraction studies to catalysts. The area of structural investigations of ionic liquids is still being developed, although growing rapidly, whereas the structure of molten salts has been studied using EXAFS in more detail.
引用
收藏
页码:29 / 49
页数:23
相关论文
共 69 条
[1]   Smectic liquid-crystalline phases of quaternary group VA (especially phosphonium) salts with three equivalent long n-alkyl chains.: How do layered assemblies form in liquid-crystalline and crystalline phases? [J].
Abdallah, DJ ;
Robertson, A ;
Hsu, HF ;
Weiss, RG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (13) :3053-3062
[2]   Extended X-ray absorption fine structure spectroscopic study of PbCl2 molten salt [J].
Ablanov, M ;
Matsuura, H ;
Takagi, R .
ELECTROCHEMISTRY, 1999, 67 (08) :839-842
[3]   A MEASUREMENT OF THE STRUCTURE OF THE SUPERIONIC CONDUCTOR COPPER(I) BROMIDE IN ITS LIQUID-PHASE BY NEUTRON-DIFFRACTION [J].
ALLEN, DA ;
HOWE, RA .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1992, 4 (28) :6029-6038
[4]  
Baston GMN, 2002, ACS SYM SER, V818, P162
[5]   COMMENTS ON THE STRUCTURE OF MOLTEN-SALTS [J].
BIGGIN, S ;
ENDERBY, JE .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1982, 15 (11) :L305-L309
[6]   STRUCTURE OF ACIDIC HALOALUMINATE MELTS - NEUTRON-DIFFRACTION AND QUANTUM CHEMICAL CALCULATIONS [J].
BLANDER, M ;
BIERWAGEN, E ;
CALKINS, KG ;
CURTISS, LA ;
PRICE, DL ;
SABOUNGI, ML .
JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (04) :2733-2741
[7]   Liquid-crystalline ionic liquids [J].
Bowlas, CJ ;
Bruce, DW ;
Seddon, KR .
CHEMICAL COMMUNICATIONS, 1996, (14) :1625-1626
[8]   Targeting IL-1 in inflammatory disease: New opportunities for therapeutic intervention [J].
Braddock, M ;
Quinn, A .
NATURE REVIEWS DRUG DISCOVERY, 2004, 3 (04) :1-10
[9]   Small-angle X-ray scattering studies of liquid crystalline 1-alkyl-3-methylimidazolium salts [J].
Bradley, AE ;
Hardacre, C ;
Holbrey, JD ;
Johnston, S ;
McMath, SEJ ;
Nieuwenhuyzen, M .
CHEMISTRY OF MATERIALS, 2002, 14 (02) :629-635
[10]   A method for studying the structure of low-temperature ionic liquids by XAFS [J].
Carmichael, AJ ;
Hardacre, C ;
Holbrey, JD ;
Nieuwenhuyzen, M ;
Seddon, KR .
ANALYTICAL CHEMISTRY, 1999, 71 (20) :4572-4574