Thallium(I) bis(mercaptoimidazolyl)borates

被引：35

作者：

Alvarez, HM

Gillespie, PA

Gause, CD

Rheingold, AL

Golen, JA

Rabinovich, D

机构：

[1] Univ N Carolina, Dept Chem, Charlotte, NC 28223 USA

[2] Johnson C Smith Univ, Dept Nat Sci & Math, Charlotte, NC 28216 USA

[3] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

POLYHEDRON | 2004年 / 23卷 / 04期

关键词：

thallium; bis(mercaptoimidazolyl)borate complexes; crystal structure;

D O I：

10.1016/j.poly.2003.10.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thallium(I) bis(mereaptoimidazolyl)borates Tl(Bm(R)) (R = Me, Bz, Bu-t, p-Tol) have been conveniently obtained in a one-pot reaction by metathesis of thallium(I) acetate and the corresponding sodium derivatives Na(Bm(R)), in turn generated in high yield from NaBH4 and the appropriate 2-mercapto-1-alkylimidazoles. In contrast to polymeric Tl(Bm(R)), the tert-butyl-substituted complex Tl(Bm(tBu)) consists of discrete dimeric molecules in the solid state, as determined by single-crystal X-ray diffraction, and is highly soluble in aromatic hydrocarbons. (C) 2003 Elsevier Ltd. All rights reserved.

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收藏

页码：617 / 622

页数：6

相关论文

共 49 条

[11]

Cassidy I, 2002, EUR J INORG CHEM, P1235

[12] Thallium(I) complexes with modified poly(pyrazolyl)borate ligands - metal-ligand coordination and crystal packing [J].

Craven, E ;

Mutlu, E ;

Lundberg, D ;

Temizdemir, S ;

Dechert, S ;

Brombacher, H ;

Janiak, C .

POLYHEDRON, 2002, 21 (5-6) :553-562

[13] Synthesis, characterization and X-ray structural studies of novel dinuclear silver(I) complexes of poly(azolyl)borate ligands [J].

Effendy ;

Lobbia, GG ;

Pettinari, C ;

Santini, C ;

Skelton, BW ;

White, AH .

INORGANICA CHIMICA ACTA, 2000, 308 (1-2) :65-72

[14]

Errington R. J., 1997, ADV PRACTICAL INORGA

[15] Poly(azolyl) chelate chemistry. Part 10 - Hydrotris(methimazolyl)borato alkylidyne complexes of tungsten [J].

Foreman, MRS ;

Hill, AF ;

White, AJP ;

Williams, DJ .

ORGANOMETALLICS, 2003, 22 (19) :3831-3840

[16] Re and Tc complexes containing B-H•••M agostic interactions as building blocks for the design of radiopharmaceuticals [J].

Garcia, R ;

Paulo, A ;

Domingos, A ;

Santos, I ;

Ortner, K ;

Alberto, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (45) :11240-11241

[17] Rhenium(I) tricarbonyl complexes with mercaptoimidazolylborate ligands bearing piperazine fragments [J].

Garcia, R ;

Xing, YH ;

Paulo, A ;

Domingos, A ;

Santos, I .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (22) :4236-4241

[18] Reactivity of [Re{k3-H(μ-H)B(timMe)2}(CO)3] (timMe = 2-mercapto-1-methylimidazolyl) toward neural substrates [J].

Garcia, R ;

Domingos, A ;

Paulo, A ;

Santos, I ;

Alberto, R .

INORGANIC CHEMISTRY, 2002, 41 (09) :2422-2428

[19] Rhenium(I) organometallic complexes with novel bis(mercaptoimidazolyl)borates and with hydrotris(mercaptoimidazolyl)borate: chemical and structural studies [J].

Garcia, R ;

Paulo, A ;

Domingos, K ;

Santos, I .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 632 (1-2) :41-48

[20] Structural and spectroscopic characterisation of bis-ligand complexes of iron(II), nickel(II) and nickel(III) with the hydrotris(methimazolyl)borate anion:: soft S6 donor sets generating a weak ligand field [J].

Garner, M ;

Lewinski, K ;

Pattek-Janczyk, A ;

Reglinski, J ;

Sieklucka, B ;

Spicer, MD ;

Szaleniec, M .

DALTON TRANSACTIONS, 2003, (06) :1181-1185

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