Vibrational structures in the A2E"←X2E′ system of the lithium trimer:: high-resolution spectroscopy and ab initio calculations

被引：28

作者：

Krämer, HG

Keil, M

Suarez, CB

Demtröder, W ^{[1
]}

Meyer, W

机构：

[1] Univ Kaiserslautern, Dept Phys, D-67653 Kaiserslautern, Germany

[2] Univ Kaiserslautern, Dept Chem, D-67653 Kaiserslautern, Germany

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 299卷 / 02期

关键词：

D O I：

10.1016/S0009-2614(98)01256-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

With narrow-band pulsed and cw lasers several vibronic bands of the A <-- X system of Li, have been measured using resonant two-photon ionization for detection. New ab initio calculations provide vibronic energies in close agreement with the measured band origins. Compared to former reports in the literature a reassignment of the electronic transition and the vibronic levels is necessary. (C) 1999 Elsevier Science B.V. AU rights reserved.

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页码：212 / 220

页数：9

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