A novel copper(I) cluster stabilized by a dithiolate ligand having a conjugated TTF moiety

被引：23

作者：

Dai, J ^{[1
]}

Munakata, M

Ohno, Y

Bian, GQ

Suenaga, Y

机构：

[1] Suzhou Univ, Dept Chem, Suzhou 215006, Peoples R China

[2] Kinki Univ, Dept Chem, Higashiosaka, Osaka 577, Japan

来源：

INORGANICA CHIMICA ACTA | 1999年 / 285卷 / 02期

关键词：

crystal structures; copper complexes; dithiolate complexes; cluster complexes;

D O I：

10.1016/S0020-1693(98)00359-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A copper(I) complex of a dithiolate ligand which is a TTF derivative has been synthesized and characterized. The structure of this complex, [Me4N](2)[Cu-4(C8H6S8)(3)]. Me2CO, is shown to be the first example of a metal cluster coordinated with a new TTF-fused dithiolate ligand. The complex is easily oxidized and shows radical properties. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：332 / 335

页数：4

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