Microwave versus conventional-hydrothermal synthesis of NaY zeolite

被引:62
作者
Katsuki, H
Furuta, S
Komarneni, S
机构
[1] Saga Ceram Res Lab, Saga 8440024, Japan
[2] Penn State Univ, Mat Res Lab, University Pk, PA 16802 USA
[3] Penn State Univ, Dept Agron, University Pk, PA 16802 USA
关键词
NaY zeolite; microwave; hydrothermal treatment; kinetics;
D O I
10.1023/A:1026583832734
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This paper focuses on the synthesis of NaY zeolite crystals by using microwave-hydrothermal (M-H) processing. NaY zeolites were synthesized from colloidal silica, sodium aluminate, sodium hydroxide and deionized water at 100 degreesC, and some properties were studied. NaY zeolite crystals with high surface area, in the range of 439 to 716 m(2)/g, have been prepared at 100 degreesC for 1 to 3 hrs. Compared to the formation of NaY zeolite via conventional-hydrothermal (C-H) treatment, the M-H treatment led to increased rate of formation by 3 to 4 times.
引用
收藏
页码:5 / 12
页数:8
相关论文
共 17 条
[1]   Gas permeation properties of A-type zeolite membrane formed on porous substrate by hydrothermal synthesis [J].
Aoki, K ;
Kusakabe, K ;
Morooka, S .
JOURNAL OF MEMBRANE SCIENCE, 1998, 141 (02) :197-205
[2]   MICROWAVE PREPARATION OF ZEOLITE-Y AND ZSM-5 [J].
ARAFAT, A ;
JANSEN, JC ;
EBAID, AR ;
VANBEKKUM, H .
ZEOLITES, 1993, 13 (03) :162-165
[3]   ON THE MECHANISM OF METHANOL CONVERSION TO HYDROCARBONS OVER HZSM-5 [J].
DESSAU, RM ;
LAPIERRE, RB .
JOURNAL OF CATALYSIS, 1982, 78 (01) :136-141
[4]   LARGE ALPO4-5 CRYSTALS BY MICROWAVE-HEATING [J].
GIRNUS, I ;
JANCKE, K ;
VETTER, R ;
RICHTERMENDAU, J ;
CARO, J .
ZEOLITES, 1995, 15 (01) :33-39
[5]  
HAGG WO, 1981, FARADY DISCUSSION CH, V72, P317
[6]   REMOVAL OF NITROGEN MONOXIDE FROM EXHAUST GASES THROUGH NOVEL CATALYTIC PROCESSES [J].
Iwamoto, Masakazu ;
Hamada, Hideaki .
CATALYSIS TODAY, 1991, 10 (01) :57-71
[7]   Hydrothermal and microwave-hydrothermal preparation of silica gels [J].
Komarneni, S ;
Menon, VC .
MATERIALS LETTERS, 1996, 27 (06) :313-315
[8]  
Komarneni S, 1998, J AM CERAM SOC, V81, P3041, DOI 10.1111/j.1151-2916.1998.tb02738.x
[9]   MICROWAVE-HYDROTHERMAL PROCESSING OF METAL POWDERS [J].
KOMARNENI, S ;
PIDUGU, R ;
LI, QH ;
ROY, R .
JOURNAL OF MATERIALS RESEARCH, 1995, 10 (07) :1687-1692
[10]   MICROWAVE-HYDROTHERMAL PROCESSING FOR SYNTHESIS OF LAYERED AND NETWORK PHOSPHATES [J].
KOMARNENI, S ;
LI, QH ;
ROY, R .
JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (12) :1903-1906