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Synthesis of indium phosphide nanoparticles via catalytic cleavage of phosphorus carbon bond in n-trioctylphosphine by indium

被引：40
作者：
Khanna, PK
Jun, KW
Hong, KB
Baeg, JO
Mehrotra, GK
机构：
[1] Korea Res Inst Chem Technol, Micro Chem Technol Lab, Taejon 305600, South Korea
[2] Ctr Mat Elect Technol, Pune 411008, Maharashtra, India
[3] MN Natl Inst Technol, Dept Chem, Allahabad 211004, Uttar Pradesh, India
来源：
MATERIALS CHEMISTRY AND PHYSICS | 2005年 / 92卷 / 01期
关键词：
indium; indium phosphide; nanoparticles; trioctylphosphine;
D O I：
10.1016/j.matchemphys.2004.12.029
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Nanocrystalline indium phosphide has been synthesized via catalytic cleavage of P-C bond in n-trioctylphosphine by indium nanoparticles at a temperature between 200 and 360 degrees C under an atmosphere of argon. Indium chloride/sodium as well as indium((0)) could be used as raw materials. The products were characterized by EDS, XRD, SEM, FESEM and PL techniques. XRD pattern of the obtained powder showed all the major peaks due to zinc blend indium phosphide with the sizes of 30-60 nm. FT-IR and TG/DTA studies indicated that InP particles were capped with TOP. (c) 2005 Elsevier B.V. All rights reserved.
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收藏
页码：54 / 58
页数：5
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