Desulfurisation of trithiocarbonates at a dimolybdenum centre: an unexpected insertion into a co-ordinated alkyne

被引：6

作者：

Adams, H ^{[1
]}

Allott, C ^{[1
]}

Bancroft, MN ^{[1
]}

Morris, MJ ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 16期

关键词：

D O I：

10.1039/a804138e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

On reaction with the dimolybdenum alkyne complex [Mo-2-{mu-C-2(CO2Me)(2)}(CO)(4)(eta-C5H5)(2)], dialkyl trithiocarbonates (RS)(2)C=S were dismantled into sulfido (mu-S), thiolate (mu-SR) and CSR fragments; remarkably the last of these inserts into the middle of the alkyne to produce a dimetalla-allyl species with a mu-C(CO2Me)C(SR)C(CO2Me) ligand.

引用

页码：2607 / 2609

页数：3

共 9 条

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