Desulfurisation and ring opening of cyclic trithiocarbonates at a dimolybdenum centre

被引：12

作者：

Adams, H ^{[1
]}

Bancroft, MN ^{[1
]}

Morris, MJ ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 15期

关键词：

D O I：

10.1039/a703336b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dimolybdenum alkyne complexes [Mo-2(mu-(RC)-C-1=CR1)(CO)(4)(eta-C5H5)(2)] (R-1 = CO2Me, Ph) react with 1,3-dithiole-2-thiones by cleavage of the C=S bond, ring opening of the resulting carbene and coupling with the alkyne ligand; one of the products, [Mo-2(mu-S)(mu-SCR2=(CRSCCRCR1)-S-2-C-1)(eta-C5H5)(2)] (R-1 = R-2 = CO2Me), is structurally characterised.

引用

页码：1445 / 1446

页数：2

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