DEALKYLATION OF THIOLS BY ALKYNE-BRIDGED DIMOLYBDENUM COMPLEXES

被引：19

作者：

ADAMS, H ^{[1
]}

BAILEY, NA ^{[1
]}

GAY, SR ^{[1
]}

HAMILTON, T ^{[1
]}

MORRIS, MJ ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期

关键词：

MOLYBDENUM; CARBONYL; THIOL; ALKYNE; VINYL; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(95)05448-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Mo-2(CO)(4){mu-C-2)(CO(2)Me)(2)}(eta-C5H5)(2)] with RSH produces the mu-vinyl complexes [Mo-2(CO)(2){mu-C(CO(2)Me) = CHCO(2)Me}(mu mu-SR)(eta-C5H5)(2)] when R = Et or Pr-i but, for R = (t)Bu, dealkylation of the thiol and further hydrogenation of the alkyne occurs to give [Mo-2(mu-S)(2)(mu-eta(2),eta(1),eta(1)-cis-MeO(2)CCH = CHCO(2)Me)(eta-C5H5)(2)] in which the alkene dimethyl maleate acts as a six-electron donor ligand through its double bond and the carbonyl oxygen atoms of both CO(2)Me groups. In contrast, treatment of [Mo-2(CO)(4)(mu-C(2)Me(2))(eta-C5H5)(2)] with RSH provides a convenient new route to compounds of the type [Mo-2(mu-S)(2)(mu-SR)(2)(eta-C5H5)(2)] when R = Et or(1)Pr.

引用

页码：C25 / C28

页数：4

共 12 条

[1] DEALKYLATION OF THIOLS BY A PHOSPHIDO-BRIDGED DIMOLYBDENUM COMPLEX - CRYSTAL-STRUCTURE OF [MO2(MU-S)2(MU-SIPR)(MU-PPH2)(ETA-C5H5)2]
ADAMS, H
BAILEY, NA
BISSON, AP
MORRIS, MJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 444 (1-2) : C34 - C36
[2] ADAMS H, IN PRESS
[3] REACTIONS OF METAL-TO-METAL MULTIPLE BONDS .4. MU-ACETYLENE-BIS(CYCLOPENTADIENYL)TETRACARBONYLDIMOLYBDENUM COMPOUNDS - PREPARATIONS, PROPERTIES, STRUCTURAL CHARACTERIZATIONS, AND DYNAMICAL SOLUTION BEHAVIOR
BAILEY, WI
CHISHOLM, MH
COTTON, FA
RANKEL, LA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (18) : 5764 - 5773
[4] THIOLATO-BRIDGED DIMOLYBDENUM COMPLEXES WITH METAL-METAL BOND ORDERS OF 0 AND 2 - X-RAY STRUCTURES OF [MO2(CO)4(MU-SPH)2(ETA-C5H5)2].0.5-[MO2(SPH)2(O)2(MU-O)(ETA-C5H5)2] AND "[MO2(CO)2(MU-SBU-TERT)2(ETA-C5H5)2]
BENSON, IB
KILLOPS, SD
KNOX, SAR
WELCH, AJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (23) : 1137 - 1139
[5] SYNGAS AND HDS CATALYSTS DERIVED FROM SULFIDO BIMETALLIC CLUSTERS
CURTIS, MD
PENNERHAHN, JE
SCHWANK, J
BARALT, O
MCCABE, DJ
THOMPSON, L
WALDO, G
[J]. POLYHEDRON, 1988, 7 (22-23) : 2411 - 2420
[6] CATALYTIC APPLICATIONS OF TRANSITION-METAL COMPLEXES WITH SULFIDE LIGANDS
DUBOIS, MR
[J]. CHEMICAL REVIEWS, 1989, 89 (01) : 1 - 9
[7] TICL4 DIESTER COMPLEXES - RELATIONSHIPS BETWEEN THE CRYSTAL-STRUCTURES AND PROPERTIES OF ZIEGLER-NATTA CATALYSTS
KAKKONEN, HJ
PURSIAINEN, J
PAKKANEN, TA
AHLGREN, M
IISKOLA, E
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 453 (02) : 175 - 184
[8] MAYS MJ, 1986, J CHEM SOC CHEM COMM, P542
[9] RAKOWSKI M, 1980, J AM CHEM SOC, V102, P7456
[10] DESULFURIZATION OF ORGANIC SULFUR-COMPOUNDS MEDIATED BY A MOLYBDENUM/COBALT/SULFUR CLUSTER
RIAZ, U
CURNOW, OJ
CURTIS, MD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (10) : 4357 - 4363

← 1 2 →