Isolation and single X-ray crystal structure of a flattened M3L2 type metallosupramolecular cage obtained by self-assembly of tripodal ligand with zinc(II) chloride

被引:5
作者
Sun, WY [1 ]
Xie, J
Yu, KB
机构
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Chinese Acad Sci, Chengdu Branch, Anal Ctr, Chengdu 610041, Peoples R China
关键词
D O I
10.1246/cl.2001.342
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel cake-like complex, Zn-3(tbib)(2)Cl-6. 3DMF . 2H(2)O [tbib = 1,3,5-tris(benzimidazol-2-ylmethyl)benzene], was synthesized by self-assembly of tripodal ligand tbib with zinc(II) chloride. The X-ray crystal structural analysis indicates that the framework is a flattened M3L2 type cage-like complex in which the tbib ligand has a cis, trans, trans conformation.
引用
收藏
页码:342 / 343
页数:2
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