Force-detected magnetic resonance without field gradients

被引:32
作者
Leskowitz, GM [1 ]
Madsen, LA [1 ]
Weitekamp, DP [1 ]
机构
[1] CALTECH, Arthur Amos Noyes Lab Chem Phys, Pasadena, CA 91125 USA
基金
美国国家航空航天局; 美国国家科学基金会;
关键词
NMR; force detection; high resolution; sensitivity;
D O I
10.1016/S0926-2040(97)00098-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel method of nuclear magnetic resonance (NMR) is described which promises to be preferable to known general methods at sample length scales below similar to 100 mu m. Its advantages stem from the seemingly paradoxical combination of a homogeneous static magnetic field and detection of a mechanical force between a spin-bearing sample and a magnet assembly. In contrast to other methods of force-detected nuclear magnetic resonance (FDNMR), the method is characterized by better observation of magnetization, enhanced resolution, and no gradient (BOOMERANG), and it is generally applicable with respect to sample composition, pulse sequence, and magnetic field strength. Further advantages of portability and low cost stem from the small instrument volume and mass and promise to extend the use of NMR to new applications and environments. A sensitivity analysis, relevant to spectroscopy or imaging, quantifies the advantage of BOOMERANG relative to magnetic induction using microcoils and to FDNMR methods that rely on large gradients of the magnetic field at the sample. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:73 / 86
页数:14
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