Convenient synthesis of copper(I) thiolates and related compounds

被引：46

作者：

Nguyen, LM

Dellinger, ME

Lee, JT

Quinlan, RA

Rheingold, AL

Pike, RD

机构：

[1] Coll William & Mary, Dept Chem, Williamsburg, VA 23187 USA

[2] Univ Calif San Diego, Dept Chem, La Jolla, CA 92093 USA

来源：

INORGANICA CHIMICA ACTA | 2005年 / 358卷 / 04期

基金：

美国国家科学基金会;

关键词：

copper (I); thiolates; phosphines; dithiocarbarnates; dithiophosphates; tetrakis(1-imidazolyl)borate;

D O I：

10.1016/j.ica.2004.11.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper (1) salts of various anions including thiolates, diethyl dithiocarbamate, diethyl dithiophosphate, trithiocyanurate, 1-cyano-3-methylisothiourea, 2-aminothiazole, and tetrakis(I-imidazolyl)borate are conveniently synthesized by reducing copper (11) sulfate in aqueous ammonia. The addition of phosphine ligands to several of the products is demonstrated, and the crystal structure Of [Cu-2(MBT)(2)(DPPE)(3)] center dot Et2O (MBT = 2-mercaptobenzothiazolate, DPPE = 1,2-bis(diphenylphosphino)ethane) is reported. (c) 2004 Elsevier B.V. All rights reserved.

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收藏

页码：1331 / 1336

页数：6

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