Structural and functional evolution of metallacrowns

被引：458

作者：

Mezei, Gellert

Zaleski, Curtis M.

Pecoraro, Vincent L. ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Williard H Dow Lab, Ann Arbor, MI 48108 USA

[2] Shippensburg Univ, Franklin Sci Ctr, Dept Chem, Shippensburg, PA 17257 USA

来源：

CHEMICAL REVIEWS | 2007年 / 107卷 / 11期

关键词：

D O I：

10.1021/cr078200h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A class of molecules known as metallacrowns is the main focus in this review. Metallacrowns, named on the basis of the ring size and the number of donating oxygen atoms, have been used or an assortment of functions such as antibacterial compounds, building two- and three-dimensional solids, stabilization of unstable molecules, single-molecule magnets as well as molecular, cation and anion recognition agents. The two aspects of metallacrown chemistry: the expanse of metallacrown structures and the numerous functions of metallacrowns, are also included in this review.

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页码：4933 / 5003

页数：71

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