Catalytic transfer hydrogenation of unsaturated ketones and imides via ammonium formate

被引：7

作者：

Pande, PP ^{[1
]}

Joshi, GC

Mathela, CS

机构：

[1] Indian Inst Petr, Dehra Dun 248005, Uttar Pradesh, India

[2] Kumaun Univ, Dept Chem, Naini Tal 263002, India

来源：

SYNTHETIC COMMUNICATIONS | 1998年 / 28卷 / 22期

关键词：

D O I：

10.1080/00397919809458700

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ammonium formate in acetic acid in presence of Pd-C catalyst efficiently converts open chain alpha,beta-unsaturated ketones and cyclic enones to their saturated ketone analogues. The system converts enimides to saturated imides. An unsaturated non-conjugated cyclic dienone was also reduced by this system.

引用

页码：4193 / 4200

页数：8