Encapsulated transition metal catalysts comprising peripheral Zn(II)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

被引：84

作者：

Kleij, AW

Lutz, M

Spek, AL

van Leeuwen, PWNM

Reek, JNH

机构：

[1] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1018 WV Amsterdam, Netherlands

[2] Univ Utrecht, Dept Crystal & Struct Chem, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 29期

关键词：

D O I：

10.1039/b503708e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Encapsulated phosphane ligands can be easily constructed through coordinative interactions between Zn(II)-salphen complexes and pyridylphosphane templates; the template has a pronounced impact on the catalyst structure and consequently on the performance in the hydroformylation of 1-octene.

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收藏

页码：3661 / 3663

页数：3

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