A novel three-dimensional molybdenum(V) phosphate decorated with zinc coordination cations:: Zn[MoO6O12(OH)3(PO4)4]2 {Zn4(H2O)5(2,2′-bipy)2}2 • 2H2O

被引：29

作者：

Guo, HX

Liu, SX ^{[1
]}

机构：

[1] Fuzhou Univ, Dept Chem, Fujian 350002, Peoples R China

[2] Zhangzhou Teachers Coll, Dept Chem, Zhangzhou 363000, Peoples R China

[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2005年 / 751卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

molybdenum(V) phosphate; zinc complex; crystal structure; 3D network;

D O I：

10.1016/j.molstruc.2005.05.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel three-dimensional molybdenum(V) phosphate decorated with zinc complex cations, Zn[Mo6O12(OH)(3)(PO4)(4)](2){Zn-4(H2O)(5)(2,2 '-bipy)(2)}(2)-2H(2)O (2,2 '-bipy=2,2 '-bipyridine) 1, has been hydrothermally synthesized and characterized by single crystal X-ray diffraction, IR, TGA and EPR spectrum. The crystal data are triclinic, space group P (1) over bar, a = 13.0842(7) angstrom, b = 14.0065(11) angstrom, c = 14.3344(10) angstrom, alpha = 64.445(3)degrees, beta = 88.805(3)degrees, gamma = 74.099(3)degrees, V=2264.9(3) angstrom(3), Z = 1, R = 0.0283, wR = 0.0749. The Zn[Mo6P4](2) units are connected together via additional zinc coordination complex ions to give a novel three-dimensional molybdenum(V) phosphate framework. (c) 2005 Elsevier B.V. All rights reserved.

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页码：156 / 160

页数：5

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