A novel 3D organic-inorganic hybrid based on sandwich-type cadmium hetereopolymolybdate:: {[Cd4(H2O)2(2,2′-bpy)2] Cd[Mo6O12(OH)3(PO4)2(HPO4)2]2} [Mo2O4(2,2′-bpy)2]2•3H2O

被引：33

作者：

Guo, HX

Liu, SX

机构：

[1] Fuzhou Univ, Dept Chem, Cent Lab, Fuzhou 350002, Peoples R China

[2] Zhangzhou Teachers Coll, Dept Chem, Zhangzhou 363000, Peoples R China

[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 11期

基金：

中国国家自然科学基金;

关键词：

heteropolyanion; cadmium; 3D network; crystal structure; hydrothermal synthesis;

D O I：

10.1016/j.inoche.2004.09.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title oreanic-inorganic hybrid cadmium molybdenum(V) phosphate has been hydrothermally synthesized. The sandwich-type units [Cd-4(H2O)(2)(2,2'-bpy)(2)]Cd[Mo6O12(OH)(3)(PO4)(2)(HPO4)(2)](2) ([Cd-4]Cd[Mo6P4](2)) are connected by octahedrally coordinated cadmium into a chain {[Cd-4]Cd[Mo6P4](2)}(n) The coordination cations [Mo2O4(2,2'-bpy)(2)](2+) link to the neighboring chains, forming a 3D open framework structure. The title complex represents the first sandwich-type cadmium hetereopolymolybdate with 3D network. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1217 / 1220

页数：4

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