An unstable ligand-unsupported CuI dimer stabilized in a supramolecular framework

被引：54

作者：

Zheng, SL ^{[1
]}

Messerschmidt, M ^{[1
]}

Coppens, P ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 29期

关键词：

copper; density functional calculations; host-guest systems; metal-metal interactions;

D O I：

10.1002/anie.200501154

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) A stable environment: A [Cu-(NH 3)2]22+ dimer with weak cuprophilicity is stabilized in the cavities of a supramolecular framework (see structure). This CuI dimer is otherwise unstable, so stabilization within a supramolecular matrix offers an unprecedented opportunity for systematic studies of the isolated dimeric species, either in the ground state or the excited state. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4614 / 4617

页数：4