Synthesis and structural characterization of tin(II) and zinc(II) derivatives of cyclic α-hydroxyketones, including the structures of Sn(maltol)2, Sn(tropolone)2, Zn(tropolone)2, and Zn(hinokitiol)2

Zinc(II) and fin(II) derivatives of maltol (Hmalt), ethylmaltol (HEtmalt), tropolone (Htrop), hinokitiol (Hhino), and kojic acid (Hkoj) have been prepared and characterized, and the crystal structures of M(trop)(2) (M = Zn, Sri) Zn(hino)(2). EtOH, and Sn(malt)2 have been determined. The Zn(trop)2 is a polymeric structure in which tropolone has both a bridging And chelating role; zinc(hino) crystallizes as an ethanol adduct of which the structure is a dimeric fragment of the Zn(trop)2 polymer and in which each metal,is "capped" by a molecule of alcohol, The in complexes are notably air-stable despite adopting monomeric pseudo-tricronal-bipyramidal structures (SnO4E; E is a stereochemically active lone electron pair) in, which the ligands only chelate a single metal center.