Dimerized nickel2+ chain compounds with nitro-nitrito bridges and unprecedented [Ln(NO3)4(CH3OH)2]- anions (Ln = lanthanide).: Crystal structure and magnetic properties

被引：14

作者：

Rajendiran, TM

Kahn, O ^{[1
]}

Golhen, S

Ouahab, L

Honda, Z

Katsumata, K

机构：

[1] Inst Chim Mat Condensee Bordeaux, Lab Sci Mol, CNRS, UPR 9048, F-33608 Pessac, France

[2] Univ Rennes 1, Chim Solide & Inorgan Mol Lab, CNRS, UMR 6511, F-35042 Rennes, France

[3] RIKEN, Inst Phys & Chem Res, Wako, Saitama 35101, Japan

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 21期

关键词：

D O I：

10.1021/ic980458q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimerization of the famous Haldane gap Ni2+ chain compound with nitro-nitrito bridges (abbreviated as NENP by the physicists) has been achieved by involving two monoanions in the structure. One of these anions, [Ln(NO3)(4)(CH3OH)(2)](-), with Ln = lanthanide element or Y, is unprecedented.

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页码：5693 / +

页数：5

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