Fabrication of Ti/TiO2/MOx electrodes using photoelectrodeposition technique

被引：7

作者：

Matsumoto, Y

Noguchi, M

Matsunaga, T

Kamada, K

Koinuma, M

Yamada, S

机构：

[1] Kumamoto Univ, Fac Engn, Dept Appl Chem, Kumamoto 8608555, Japan

[2] Teikyo Univ, Sch Sci & Engn, Dept Mat Sci & Engn, Utsunomiya, Tochigi 3208551, Japan

来源：

ELECTROCHEMISTRY | 2001年 / 69卷 / 05期

关键词：

titanium dioxide film; electrodeposition; lead dioxide; ruthenium oxide;

D O I：

10.5796/electrochemistry.69.314

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Photoelectrochemical deposition of metallic oxide (PbO2, RuOx, NiOOH, and CoOOH) onto a Ti substrate was studied and the electrochemical behavior of the prepared Ti/TiO2/MOx electrodes was examined. The photoelectrochemical deposition of MOx occurred in the solutions containing Mn+ ions on the Ti substrate under anodic bias. Electron holes produced on the TiO2 film surface under illumination may contribute the MOx formation. The prepared Ti/TiO2 /MOx electrodes showed a tunneling current under anodic bias.

引用

收藏

页码：314 / 318

页数：5

相关论文

共 29 条

[1] Mesoporous platinum films from lyotropic liquid crystalline phases [J].

Attard, GS ;

Bartlett, PN ;

Coleman, NRB ;

Elliott, JM ;

Owen, JR ;

Wang, JH .

SCIENCE, 1997, 278 (5339) :838-840

[2] BREAKDOWN AND EFFICIENCY OF ANODIC OXIDE-GROWTH ON TITANIUM [J].

DYER, CK ;

LEACH, JSL .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1978, 125 (07) :1032-1038

[3] ELECTROCATALYSIS OF ANODIC OXYGEN-TRANSFER REACTIONS - TITANIUM SUBSTRATES FOR PURE AND DOPED LEAD DIOXIDE FILMS [J].

FENG, JR ;

JOHNSON, DC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (11) :3328-3337

[4] Epitaxial size control by mismatch tuning in electrodeposited Cd(Se,Te) quantum dots on {111}gold [J].

Golan, Y ;

Hutchison, JL ;

Rubinstein, I ;

Hodes, G .

ADVANCED MATERIALS, 1996, 8 (08) :631-&

[5] Bandgap enlargement in anodic oxide films on titanium [J].

Goossens, A .

SURFACE SCIENCE, 1997, 371 (2-3) :390-398

[6] Intensity-modulated photocurrent spectroscopy of thin anodic films on titanium [J].

Goossens, A .

SURFACE SCIENCE, 1996, 365 (03) :662-671

[7] Hybrid electrochemical/chemical synthesis of supported, luminescent semiconductor nanocrystallites with size selectivity: Copper(I)iodide [J].

Hsiao, GS ;

Anderson, MG ;

Gorer, S ;

Harris, D ;

Penner, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (06) :1439-1448

[8] Cyclic voltammetric deposition of hydrous ruthenium oxide for electrochemical capacitors [J].

Hu, CC ;

Huang, YH .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (07) :2465-2471

[9] PASSIVE BEHAVIOR OF TITANIUM [J].

HURLEN, T ;

WILHELMSEN, W .

ELECTROCHIMICA ACTA, 1986, 31 (09) :1139-1146

[10] FORMATION OF PEROVSKITE STRUCTURE LA1-XCAXCRO3 FILMS WITH ELECTRODEPOSITION [J].

KONNO, H ;

TOKITA, M ;

FURUICHI, R .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (01) :361-362