Partial molar fluctuations in aqueous 2-butoxyethanol

被引:27
作者
Koga, Y [1 ]
Westh, P [1 ]
机构
[1] UNIV COPENHAGEN, DEPT CHEM, DK-2100 COPENHAGEN, DENMARK
关键词
D O I
10.1246/bcsj.69.1505
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The normalized fluctuations were reformulated in a unified manner, keeping the number of molecules in each coarse grain fixed. The normalized fluctuations were evaluated for aqueous 2-butoxyethanol using the existing data of chi(T), C-p, alpha(p), and V-m. The partial molar fluctuations of 2-butoxyethanol were then calculated. These quantities added some more evidences to the mixing schemes in aqueous 2-butoxyethanol conjectured earlier in this laboratory.
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页码:1505 / 1508
页数:4
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