Bis{(2-diphenylphosphino)phenyl}mercury:: a novel bidentate ligand and transfer reagent for the o-C6H4PPh2 group

被引:31
作者
Bennett, MA [1 ]
Contel, M [1 ]
Hockless, DCR [1 ]
Welling, LL [1 ]
机构
[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia
关键词
D O I
10.1039/a806494f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The compound [Hg(o-C6H4PPh2)(2)] behaves as a trans-spanning bidentate ditertiary phosphine in its PdCl2 complex, the two metal atoms being forced into close contact; the palladium(0) complex [Pd{(o-Ph2PC6H4)(2)Hg}(2)] undergoes reductive elimination on heating with formation of the coupled product o-Ph2PC6H4C6H4PPh2-o.
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页码:2401 / 2402
页数:2
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