Bis{(2-diphenylphosphino)phenyl}mercury:: a novel bidentate ligand and transfer reagent for the o-C6H4PPh2 group

被引：31

作者：

Bennett, MA ^{[1
]}

Contel, M ^{[1
]}

Hockless, DCR ^{[1
]}

Welling, LL ^{[1
]}

机构：

[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 21期

关键词：

D O I：

10.1039/a806494f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound [Hg(o-C6H4PPh2)(2)] behaves as a trans-spanning bidentate ditertiary phosphine in its PdCl2 complex, the two metal atoms being forced into close contact; the palladium(0) complex [Pd{(o-Ph2PC6H4)(2)Hg}(2)] undergoes reductive elimination on heating with formation of the coupled product o-Ph2PC6H4C6H4PPh2-o.

引用

页码：2401 / 2402

页数：2

共 30 条

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