One-pot, catalytic, asymmetric synthesis of polypropionates

被引：33

作者：

Calter, MA ^{[1
]}

Guo, X ^{[1
]}

Liao, WS ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 10期

关键词：

D O I：

10.1021/ol015814e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The opening of methylketene dimer, followed by aldol reactions of the resulting enolate, provides a convenient access to syn,syn-dipropionate aldol adducts of a variety of aldehydes, These aldol adducts are useful precursors in the synthesis of complex polypropionates.

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页码：1499 / 1501

页数：3

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