Chromium salen catalysed asymmetric alkene epoxidation.: Influence of substituents at the 3,3′-positions on the salen rings.

被引:53
作者
Ryan, KM [1 ]
Bousquet, C [1 ]
Gilheany, DG [1 ]
机构
[1] Natl Univ Ireland Univ Coll Dublin, Dept Chem, Dublin 4, Ireland
关键词
D O I
10.1016/S0040-4039(99)00488-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Any substituent at the 3,3'-positions is sufficient to give greater than 80% ee in the epoxidation of E-beta-methylstyrene with chromium-salen complexes. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3613 / 3616
页数:4
相关论文
共 15 条
[1]  
*ACS, 1996, 211 NAT M AM CHEM SO
[2]   CHROMIUM CATALYZED ASYMMETRIC ALKENE EPOXIDATION - GREATER SELECTIVITY FOR AN E-ALKENE VERSUS ITS Z-ISOMER [J].
BOUSQUET, C ;
GILHEANY, DG .
TETRAHEDRON LETTERS, 1995, 36 (42) :7739-7742
[3]   REGIOSELECTIVE AND ENANTIOSELECTIVE EPOXIDATION CATALYZED BY METALLOPORPHYRINS [J].
COLLMAN, JP ;
ZHANG, XM ;
LEE, VJ ;
UFFELMAN, ES ;
BRAUMAN, JI .
SCIENCE, 1993, 261 (5127) :1404-1411
[4]   Recent progress towards the understanding of metal-salen catalysed asymmetric alkene epoxidation [J].
Dalton, CT ;
Ryan, KM ;
Wall, VM ;
Bousquet, C ;
Gilheany, DG .
TOPICS IN CATALYSIS, 1998, 5 (1-4) :75-91
[5]   EPOXIDATION REACTIONS CATALYZED BY IRON PORPHYRINS - OXYGEN-TRANSFER FROM IODOSYLBENZENE [J].
GROVES, JT ;
NEMO, TE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) :5786-5791
[6]   Mechanism of one oxygen atom transfer from oxo (salen)manganese(V) complex to olefins [J].
Hamada, T ;
Fukuda, T ;
Imanishi, H ;
Katsuki, T .
TETRAHEDRON, 1996, 52 (02) :515-530
[7]  
HOSOYA N, 1991, SYNLETT, P691
[8]  
Houk KN, 1996, EL C HET CHEM ECHET9
[9]   CATALYTIC ASYMMETRIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS [J].
IRIE, R ;
NODA, K ;
ITO, Y ;
MATSUMOTO, N ;
KATSUKI, T .
TETRAHEDRON LETTERS, 1990, 31 (50) :7345-7348
[10]  
JACOBSEN EN, 1993, CATALYTIC ASYMMETRIC, P159