Physicochemical properties of metal-doped activated carbons and relationship with their performance in the removal of SO2 and NO

Several metal-doped activated carbons (Fe, Co, Ni, V, Mn, Cu and Ce) were prepared and characterized. The results of N-2 adsorption-desorption, X-ray diffraction, and X-ray photoelectron spectroscopy indicated that some metals (Cu and Fe) were partly reduced by carbon during preparation. Activity tests for the removal of SO2 and the selective catalytic reduction of NO with ammonia were carried out. Due to different physicochemical properties, different pathways for the SO2 removal had been put out, i.e., catalytic oxidation, direct reaction and adsorption. This classification depended on the standard reduction potentials of metal redox pairs. Samples impregnated with V. Ce and Cu showed good activity for NO reduction by NH3, which was also ascribed to the reduction potential values of metal redox pairs. Ce seemed to be a promising alternative to V due to the higher activity in NO reduction and the nontoxic property. A metal cation which could easily convert between the two valences seemed to be crucial to the good performance of both SO2 and NO removal, just like V and Cu. (C) 2011 Elsevier B.V. All rights reserved.