Colloid particle adsorption in the slot impinging jet cell

被引:17
作者
Adamczyk, Z [1 ]
Szyk, L [1 ]
Warszynski, P [1 ]
机构
[1] Polish Acad Sci, Inst Catalysis & Surface Chem, PL-30239 Krakow, Poland
关键词
particle adsorption; kinetics of particle adsorption; localized adsorption; slot impinging jet adsorption; surface blocking effects;
D O I
10.1006/jcis.1998.5907
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A detailed description of flow distribution in the slot impinging jet cell (SIJ) is presented. Numerical solutions of the governing Navier-Stokes equation showed that for Re < 30 the flow resembles closely the one occurring near a cylinder placed in a uniform how, It was also shown that for tangential distances x/d < 0.25 the flow configuration in the vicinity of the solid can be approximated by the plane-parallel stagnation flow with the perpendicular velocity component independent of this distance. This flow field was used for deriving the mass transfer equation, which was then numerically solved to obtain the initial flux (adsorption rate) for various transport conditions, These theoretical predictions were verified experimentally using polystyrene latex particles of the size 1 and 1.48 mu m A good agreement between predicted and measured initial flux values was found for a broad range of Reynolds number and ionic strength of the particle suspension. This confirmed that the SIJ cell surface was uniformly accessible for particles at distances x/d < 0.5, At larger distances a systematic deviation from uniform deposition rates was observed, becoming important for higher coverages and Re. This effect was attributed to the hydrodynamic scattering of adsorbing particles on particles already attached to the surface, This phenomenon was quantitatively accounted for by the Brownian dynamics type simulations, (C) 1999 Academic Press.
引用
收藏
页码:350 / 361
页数:12
相关论文
共 35 条
[11]   APPROXIMATE METHODS OF DETERMINING DOUBLE-LAYER FREE ENERGY OF INTERACTION BETWEEN 2 CHARGED COLLOIDAL SPHERES [J].
BELL, GM ;
LEVINE, S ;
MCCARTNE.LN .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1970, 33 (03) :335-&
[12]   Kinetics of particle adsorption in stagnation point flow studied by optical reflectometry [J].
Bohmer, MR ;
van der Zeeuw, EA ;
Koper, GJM .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1998, 197 (02) :242-250
[13]   THE SLOW MOTION OF A SPHERE THROUGH A VISCOUS FLUID TOWARDS A PLANE SURFACE [J].
BRENNER, H .
CHEMICAL ENGINEERING SCIENCE, 1961, 16 (3-4) :242-251
[14]  
DABROS T, 1987, PHYSICOCHEM HYDRODYN, V8, P161
[15]   INTERPARTICLE HYDRODYNAMIC INTERACTIONS IN DEPOSITION PROCESSES [J].
DABROS, T .
COLLOIDS AND SURFACES, 1989, 39 (1-3) :127-141
[16]   A DIRECT METHOD FOR STUDYING PARTICLE DEPOSITION ONTO SOLID-SURFACES [J].
DABROS, T ;
VANDEVEN, TGM .
COLLOID AND POLYMER SCIENCE, 1983, 261 (08) :694-707
[17]   SURFACE COLLISIONS IN A VISCOUS-FLUID [J].
DABROS, T ;
VANDEVEN, TGM .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1992, 149 (02) :493-505
[18]   KINETICS OF COATING BY COLLOIDAL PARTICLES [J].
DABROS, T ;
VANDEVEN, TGM .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1982, 89 (01) :232-244
[19]   KINETICS OF POLYMER ADSORPTION IN STAGNATION POINT FLOW [J].
DIJT, JC ;
STUART, MAC ;
HOFMAN, JE ;
FLEER, GJ .
COLLOIDS AND SURFACES, 1990, 51 :141-158
[20]   REFLECTOMETRY AS A TOOL FOR ADSORPTION STUDIES [J].
DIJT, JC ;
STUART, MAC ;
FLEER, GJ .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1994, 50 :79-101