Electronic structure of the NaN2 and NaC2H2 collision complexes:: Experiment and theory

被引：10

作者：

Goldstein, R ^{[1
]}

Grosser, J

Hoffmann, O

Schumann, V

Wössner, D

Jungen, M

Lehner, M

机构：

[1] Univ Hannover, Inst Atom & Mol Phys, D-30167 Hannover, Germany

[2] Univ Basel, Inst Phys Chem, CH-4056 Basel, Switzerland

来源：

JOURNAL OF CHEMICAL PHYSICS | 2001年 / 114卷 / 05期

关键词：

D O I：

10.1063/1.1337060

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electronic structure of the NaN2 and NaC2H2 collision pairs is probed by optical excitation. Based on polarization experiments, we measure the alignment tensor of the electronic transition dipole moments. We compare the experimental data with the results of a quantum chemical calculation. The different geometric properties of the electronic wave functions of the two collision pairs are directly visible in the experimental data. (C) 2001 American Institute of Physics.

引用

页码：2144 / 2148

页数：5

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