Oxidative decomposition of chlorinated hydrocarbons by glow discharge in PACT (plasma and catalyst integrated technologies) reactors

被引：20

作者：

Chen, X

Rozak, J

Lin, JC

Suib, SL ^{[1
]}

Hayashi, J

Matsumoto, H

机构：

[1] Univ Connecticut, Dept Chem, Storrs, CT 06269 USA

[2] Univ Connecticut, Dept Chem Engn, Storrs, CT 06269 USA

[3] Univ Connecticut, Inst Mat Sci, Dept Chem & Chem Engn, Storrs, CT 06269 USA

[4] Fujitsu Labs Ltd, Nakahara 211, Japan

[5] Nagasaki Univ, Dept Chem, Nagasaki 852, Japan

来源：

APPLIED CATALYSIS A-GENERAL | 2001年 / 219卷 / 1-2期

关键词：

plasma; chlorinated hydrocarbons; decomposition; methyl chloride; methylene chloride;

D O I：

10.1016/S0926-860X(01)00644-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidative decomposition of methyl chloride (CH3Cl) and methylene chloride (CH2Cl2) by glow discharge has been carried out in a new type of reactor using plasma and catalyst integrated technologies (PACT) in our laboratory. The PACT reactors with metal (Fe, Pt, or Au) coated electrodes were used in our experiments at room temperature and atmospheric pressure. Feed compositions were 5000 ppm of either CH3Cl or CH2Cl2 and 5% of oxygen with a balance of helium and a total flow rate of around 20 ml/min. Significant conversions (as high as 90%) of CH3Cl or CH2Cl2 have been achieved for the oxidative decomposition of CH3Cl or CH2Cl2 Using PACT reactors. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：25 / 31

页数：7

共 24 条

[1]

ALEKSANDROV NL, 1995, PLASMA CHEM PLASMA P, V15, P529

[2]

ALEKSANDROV NL, 1994, PLASMA PHYS REP, V20, P442

[3]

Brook SL, 1998, J CATAL, V180, P225

[4] OXIDATIVE CATALYSIS OF CHLORINATED HYDROCARBONS BY METAL-LOADED ACID CATALYSTS [J].