Heterogeneous catalysis - Oxidant-free alcohol dehydrogenation using a reusable hydrotalcite-supported silver nanoparticle catalyst

被引：264

作者：

Mitsudome, Takato ^{[1
]}

Mikami, Yusuke ^{[1
]}

Funai, Hisashi ^{[1
]}

Mizugaki, Tomoo ^{[1
]}

Jitsukawa, Koichiro ^{[1
]}

Kaneda, Kiyotomi ^{[1
,2
]}

机构：

[1] Osaka Univ, Dept Mat Engn Sci, Grad Sch Engn Sci, Osaka 5608531, Japan

[2] Osaka Univ, Res Ctr Solar Energy Chem, Osaka 5608531, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 01期

关键词：

alcohols; dehydrogenation; heterogeneous catalysis; nanoparticles; silver;

D O I：

10.1002/anie.200703161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Additive free: Hydrotalcite-supported silver nanoparticles act as a highly efficient heterogeneous catalyst for the dehydrogenation of diverse alcohols (see picture) in the absence of any acceptors such as molecular oxygen, hydrogen peroxide, or unsaturated organic compounds. The solid Ag catalyst was readily reusable without any loss of activity and selectivity. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：138 / 141

页数：4

共 42 条

[31] Alcohol selective oxidation over modified foam-silver catalysts [J].