Synthesis of ferrocene/hydrofullerene hybrid and functionalized bucky ferrocenes

被引：73

作者：

Toganoh, M ^{[1
]}

Matsuo, Y ^{[1
]}

Nakamura, E ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 46期

关键词：

D O I：

10.1021/ja037335b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydroferration reaction of [60]fullerene or its derivative with [Fe(C5H5)(CO)2]2 gives regioselectively a ferrocene/hydrofullerene hybrid, which upon treatment with Bu4NOH and an alkyl halide affords the corresponding alkylated bucky ferrocene, again regioselectivity via an anion of the ferrocene. Copyright © 2003 American Chemical Society.

引用

页码：13974 / 13975

页数：2

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