Cu(II)- and Hg(II)-induced modulation of the fluorescence behavior of a redox-active sensor molecule

被引：122

作者：

Hennrich, G

Walther, W

Resch-Genger, U

Sonnenschein, H

机构：

[1] Fed Inst Mat Res & Testing, D-12489 Berlin, Germany

[2] Inst Nonclass Chem, D-04303 Leipzig, Germany

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 04期

关键词：

D O I：

10.1021/ic000827u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Here, we report on a fluorescent 1,2,4-thiadiazole derivative (oxidized form) and its reduced form, the corresponding iminoyl thiourea. The thiadiazole displays a strong modulation of its fluorescence behavior, selectively upon addition of Cu(II), while the iminoyl thiourea functions as a chemodosimeter for Hg(II). Additionally, the Cu(II)-thiadiazole complex is characterized by HRMS, and the HE(II)-induced desulfurization of the iminoyl thiourea is monitored by mass spectrometry.

引用

页码：641 / 644

页数：4