A luminescent polymeric complex containing ten-nuclear platinum-silver '[Pt2Ag8(CCBut)8(OClO3)2(acetone)2]+2' cations in the backbone

被引:25
作者
Ara, I
Forniés, J [1 ]
Gomez, J
Lalinde, E
Merino, RI
Moreno, MT
机构
[1] Univ Zaragoza, Dept Quim Inorgan, Inst Ciencia Mat Aragon, CSIC, E-50009 Zaragoza, Spain
[2] Univ La Rioja, Dept Quim, Logrono 26001, Spain
关键词
polymeric; platinum; silver; alkynyl; luminescence;
D O I
10.1016/S1387-7003(99)00011-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel platinum-silver alkynyl polymeric complex {[Pt2Ag8(C=CBu')(8)(OClO3)(2)(acetone)(2)] (O2ClO2)(2)}(n) (2) has been obtained by reaction of [Pt2Ag4(C=CBu')(8)] (1) with AgClO4. Its X-ray structure and optical properties (both complexes being luminescent) are reported. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:62 / 65
页数:4
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