Methylated and phenylated C60 from fluorinated fullerene precursors

被引：13

作者：

Mickelson, ET

Hauge, RH

Margrave, JL

机构：

[1] Rice Univ, Dept Chem, Houston, TX 77005 USA

[2] Rice Univ, Rice Quantum Inst, Houston, TX 77005 USA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 92卷 / 01期

关键词：

C-60; fluorination; methylation; phenylation;

D O I：

10.1016/S0022-1139(98)00243-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

C-60 has been fluorinated with F-2 to yield a product which consists mostly of C60F44. This species was then reacted with methyl and phenyl lithium reagents to yield the respective methylated and phenylated nucleophilic substitution products. These products have been confirmed and characterized by IR, H-1-NMR and mass spectroscopies. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：59 / 62

页数：4

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