A one-pot synthesis of primary amides from aldoximes or aldehydes in water in the presence of a supported rhodium catalyst

被引：150

作者：

Fujiwara, Hiroshi ^{[1
]}

Ogasawara, Yoshiyuki ^{[1
]}

Yamaguchi, Kazuya ^{[1
]}

Mizuno, Noritaka ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 27期

关键词：

aldehydes; amides; heterogeneous catalysis; rhodium; supported catalysts;

D O I：

10.1002/anie.200701273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Equation Presented) Dehydration/Rehydration in Water: Supported rhodium hydroxide (Rh(OH)x/ Al2O3) is an effective heterogeneous catalyst for the synthesis of primary amides from aldoximes and aldehydes in water in a reaction that is entirely free of hazardous and carcinogenic organic solvents (see scheme). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5202 / 5205

页数：4

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