Halogen bonding interactions with the [Mo3S7Cl6]2- cluster anion in the mixed valence salt [EDT-TTFI2]4[Mo3S7Cl6]•CH3CN

被引:21
作者
Alberola, Antonio [2 ]
Fourmigue, Marc [1 ]
Gomez-Garcia, Carlos J. [3 ]
Llusar, Rosa [2 ]
Triguero, Sonia [2 ]
机构
[1] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France
[2] Univ Jaume 1, Dept Quim Fis & Analit, E-12071 Castellon de La Plana, Spain
[3] Univ Valencia, Inst Ciencia Mol, E-46980 Paterna, Spain
关键词
D O I
10.1039/b800298c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrocrystallization of iodinated TTF molecules in presence of trinuclear [Mo3S7Cl6](2-) cluster anions provides the first example of radical salts with halogen bonding interactions at the organic/inorganic interface.
引用
收藏
页码:1103 / 1109
页数:7
相关论文
共 75 条
[1]   Structural diversity in charge transfer salts based on Mo3S7 and Mo3S4Se3 clusters complexes and bis(ethylenedithio)tetrathiafulvalene (ET) [J].
Alberola, Antonio ;
Llusar, Rosa ;
Triguero, Sonia ;
Vicent, Cristian ;
Sokolov, Maxim N. ;
Gomez-Garcia, Carlos .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (32) :3440-3450
[2]  
[Anonymous], 1999, J. Appl. Crystallogr, DOI [DOI 10.1107/S0021889899006020, 10.1107/S0021889899006020]
[3]   ANTIPEROVSKITE STRUCTURE WITH TERNARY TETRATHIAFULVALENIUM SALTS - CONSTRUCTION, DISTORTION, AND ANTIFERROMAGNETIC ORDERING [J].
BATAIL, P ;
LIVAGE, C ;
PARKIN, SSP ;
COULON, C ;
MARTIN, JD ;
CANADELL, E .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (11) :1498-1500
[4]   Electrocrystallization, an invaluable tool for the construction of ordered, electroactive molecular solids [J].
Batail, P ;
Boubekeur, K ;
Fourmigue, M ;
Gabriel, JCP .
CHEMISTRY OF MATERIALS, 1998, 10 (10) :3005-3015
[5]  
BATAIL P, 2004, CHEM REV, V11, P104
[6]   Structural isomerism in crystals of redox-active secondary ortho-diamides:: The role of competing intra- and intermolecular hydrogen bonds in directing crystalline topologies [J].
Baudron, SA ;
Avarvari, N ;
Canadell, E ;
Auban-Senzier, P ;
Batail, P .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (18) :4498-4511
[7]   Singular crystalline β′-Layered topologies directed by ribbons of self-complementary amide ••• amide ring motifs in [EDT-TTF-(CONH2)2]2X (X = HSO4-, ClO4-, ReO4-, AsF6-):: Coupled activation of ribbon curvature, electron interactions, and magnetic susceptibility [J].
Baudron, SA ;
Avarvari, N ;
Batail, P ;
Coulon, C ;
Clérac, R ;
Canadell, E ;
Auban-Senzier, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (38) :11583-11590
[8]   Reactivity of the [Mo3(μ3-S)(μ2-S2)3Br6]2- anion toward the imidodiphosphinochalcogenido ligands [N(QPPh2)2]- (Q = S, Se):: Synthesis and characterization of [Mo3(μ3-S)(μ2-S2)3{N(QPPh2)2}3]Br [J].
Béreau, V ;
Pernin, CG ;
Ibers, JA .
INORGANIC CHEMISTRY, 2000, 39 (04) :854-+
[9]   A CONSTRUCTION PRINCIPLE OF THE K-PHASE BASED ON THE EFFICIENT (O-H)DONOR ...OANION STRUCTURAL FUNCTIONALITY - THE EXAMPLES OF K-(EDT-TTF(CH2OH))2X(X = CLO4-CIRCLE-MINUS AND REO4-CIRCLE-MINUS) [J].
BLANCHARD, P ;
BOUBEKEUR, K ;
SALLE, M ;
DUGUAY, G ;
JUBAULT, M ;
GORGUES, A ;
MARTIN, JD ;
CANADELL, E ;
AUBANSENZIER, P ;
JEROME, D ;
BATAIL, P .
ADVANCED MATERIALS, 1992, 4 (09) :579-581
[10]   ANOMALOUS PARAMAGNETISM OF COPPER ACETATE [J].
BLEANEY, B ;
BOWERS, KD .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1952, 214 (1119) :451-465