Nitrosyl, nitro, and nitrato complexes of palladium(IV).: The first structurally characterized mononuclear nitrosyl complex of palladium

被引:51
作者
Cámpora, J
Palma, P
del Río, D
Carmona, E
Graiff, C
Tiripicchio, A
机构
[1] Univ Sevilla, CSIC, Inst Invest Quim, Seville 41092, Spain
[2] Univ Parma, Dipartimento Chim Gen Inorgan Chim Analit Chim Fi, CNR, Ctr Studio Strutturist Diffrattometr, I-43100 Parma, Italy
关键词
D O I
10.1021/om030170v
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of Pd-IV-(NOx) complexes (x = 1, nitrosyl; x = 2, nitro; x = 3, nitrate) has been synthesized. The nitrosyl derivative [Pd(CH2CMe2-o-C6H4)(kappa(3)-Tp)-(NO)] is the first palladium mononuclear derivative to be structurally characterized by X-ray diffraction methods.
引用
收藏
页码:3345 / 3347
页数:3
相关论文
共 33 条