Nitrosyl, nitro, and nitrato complexes of palladium(IV).: The first structurally characterized mononuclear nitrosyl complex of palladium

被引:51
作者
Cámpora, J
Palma, P
del Río, D
Carmona, E
Graiff, C
Tiripicchio, A
机构
[1] Univ Sevilla, CSIC, Inst Invest Quim, Seville 41092, Spain
[2] Univ Parma, Dipartimento Chim Gen Inorgan Chim Analit Chim Fi, CNR, Ctr Studio Strutturist Diffrattometr, I-43100 Parma, Italy
关键词
D O I
10.1021/om030170v
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of Pd-IV-(NOx) complexes (x = 1, nitrosyl; x = 2, nitro; x = 3, nitrate) has been synthesized. The nitrosyl derivative [Pd(CH2CMe2-o-C6H4)(kappa(3)-Tp)-(NO)] is the first palladium mononuclear derivative to be structurally characterized by X-ray diffraction methods.
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收藏
页码:3345 / 3347
页数:3
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共 33 条
  • [11] The first nitrosyl complexes of niobium and tantalum
    Daff, PJ
    Legzdins, P
    Rettig, SJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (11) : 2688 - 2689
  • [12] DELRIO D, 2003, THESIS U SEVILLE
  • [13] PRINCIPLES OF STRUCTURE, BONDING, AND REACTIVITY FOR METAL NITROSYL COMPLEXES
    ENEMARK, JH
    FELTHAM, RD
    [J]. COORDINATION CHEMISTRY REVIEWS, 1974, 13 (04) : 339 - 406
  • [14] Feltham R.D., 1981, TOPICS INORGANIC ORG, V12, P155
  • [15] Mechanistic aspects of the reactions of nitric oxide with transition-metal complexes
    Ford, PC
    Lorkovic, IM
    [J]. CHEMICAL REVIEWS, 2002, 102 (04) : 993 - 1017
  • [16] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE BENT NITROSYL ORGANOMETALLIC COMPLEX [NBU4][PT(C6CL5)2CL2(NO)]
    FORNIES, J
    MENJON, B
    SANZCARRILLO, RM
    TOMAS, M
    [J]. CHEMISCHE BERICHTE, 1994, 127 (04) : 651 - 652
  • [17] FORNITCHEV DV, 1998, INORG CHEM, V37, P1519
  • [18] 4-COORDINATE METAL NITROSYLS .2. STRUCTURES OF NIX(NO)(P(C6H5)3)2 COMPLEXES
    HALLER, KJ
    ENEMARK, JH
    [J]. INORGANIC CHEMISTRY, 1978, 17 (12) : 3552 - 3558
  • [19] Coordination and organometallic chemistry of metal-NO complexes
    Hayton, TW
    Legzdins, P
    Sharp, WB
    [J]. CHEMICAL REVIEWS, 2002, 102 (04) : 935 - 991
  • [20] Synthesis, characterization, and solution redox properties of (trimpsi)M(CO)2(NO) complexes [M = V, Nb, Ta; trimpsi = tBuSi(CH2PMe2)3]
    Hayton, TW
    Daff, PJ
    Legzdins, P
    Rettig, SJ
    Patrick, BO
    [J]. INORGANIC CHEMISTRY, 2002, 41 (16) : 4114 - 4126