Investigation of enantiomer bonding on a chiral stationary phase by FT-Raman spectrometry

被引：13

作者：

Horváth, E

Kocsis, L

Frost, RL

Hren, B

Szabó, LP

机构：

[1] Hungarian Acad Sci, Res Grp Analyt Chem, H-8201 Veszprem, Hungary

[2] Queensland Univ Technol, Ctr Instrumental & Dev Chem, Brisbane, Qld 4001, Australia

[3] Univ Veszprem, Dept Analyt Chem, H-8201 Veszprem, Hungary

[4] Hungarian Acad Sci, Res Inst Chem Engn, H-8201 Veszprem, Hungary

来源：

ANALYTICAL CHEMISTRY | 1998年 / 70卷 / 13期

关键词：

D O I：

10.1021/ac9712411

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The bonding of serine, phenylalanine, and mandelic acid enantiomers on an N-3,5-dinitrobenzoyl-L-leucine chiral stationary phase (on zeolite A support) has been investigated by FT-Raman spectrometry. It was found that retention is due to hydrogen bonds and pi-stacking interactions between the stationary phase and the analyte. The involvement of the two different amide groups (as donor and/or acceptor) in the complexation reaction can be followed based on spectral data. A correlation was found between the ratio of the amide I and the ring stretching (1532 cm(-1)) bands and retention data.

引用

页码：2766 / 2770

页数：5

共 15 条

[1]

DORSEY JG, 1992, ANAL CHEM, V64, pR353

[2] MICROCOLUMN HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY THIN-LAYER CHROMATOGRAPHY FOURIER-TRANSFORM INFRARED SPECTROMETRY [J].