Bimetallic Ru-Sn nanoparticle catalysts for the solvent-free selective hydrogenation of 1,5,9-cyclododecatriene to cyclododecene

被引：79

作者：

Adams, Richard D. ^{[1
]}

Boswell, Erin M.

Captain, Burjor

Hungria, Ana B.

Midgley, Paul A.

Raja, Robert

Thomas, John Meurig

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

[2] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England

[3] Univ Cambridge, Dept Mat Sci, Cambridge CB2 3QZ, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 43期

关键词：

Bimetallic clusters; Electron microscopy; Heterogeneous catalysis; Hydrogenation; Nanoparticles;

D O I：

10.1002/anie.200702274

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Tin(n)y catalysts: Bimetallic RuSn supported nanoparticle catalysts (see picture; Ru green, Sn blue, O red), prepared from the carbonyl-cluster precursors [Ru4 (μ4-SnPh) 2(μ-SnPh2)4-x(CO)12-x] (x = 0, 2, 3, 4) are shown to be active catalysts for the highly selective hydrogenation of 1,5,9-cyclododecatriene to cyclododecene under mild conditions. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8182 / 8185

页数：4

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