Unique structural isomerism involving tetrazole and amide/azide derivatives of gallium

被引:49
作者
Hardman, NJ [1 ]
Power, PP [1 ]
机构
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
关键词
D O I
10.1039/b100466m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction between {HC(MeCDippN)(2)}Ga: (Dipp = C6H3Pr2i-2,6) and N3SiMe3 afforded the tetrazole {HC(MeCDippN)(2)}GaN(SiMe3)NNN(SiMe3) 1 and its amide/azide isomer {HC(MeCDippN)(2)}Ga(N-3)N(SiMe3)(2) 2 whose stabilities are due to the unique steric properties of the [HC(MeCDippN)(2)](-) ligand.
引用
收藏
页码:1184 / 1185
页数:2
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