Triangular geometrical and magnetic motifs uniquely linked on a spherical capsule surface

被引：123

作者：

Müller, A

Todea, AM

van Slageren, J

Dressel, M

Bögge, H

Schmidtmann, M

Luban, M

Engelhardt, L

Rusu, M

机构：

[1] Univ Bielefeld, Fak Chem, Lehrstuhl Anorgan Chem 1, D-33501 Bielefeld, Germany

[2] Univ Stuttgart, Inst Phys 1, D-70550 Stuttgart, Germany

[3] Iowa State Univ, Ames Lab, Ames, IA 50011 USA

[4] Iowa State Univ, Dept Phys & Astron, Ames, IA 50011 USA

[5] Univ Babes Bolyai, Fac Chem, R-3400 Cluj Napoca, Romania

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 25期

关键词：

magnetochemistry; mixed-valence compounds; molybdenum; polyoxometalates; vanadium;

D O I：

10.1002/anie.200500697

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sphere we go: A spherical capsule is prepared simply by the interaction of linkers to pentagonal structural units. The metal centers (M) of the {(Mo VI)MoVI 5}12-M30 type Keplerates formed (M=VIV, FeIII) describe an icosidodecahedron (see picture). For M = FeIII the magnetic configuration of the 30 spin centers (colored spheres) can be pictured geometrically in terms of three sets, each of 10 spins, with different angular orientations (arrows). With M =VIV the compound behaves according to the demands of quantum mechanics and a clear geometrical picture of the magnetism is not possible. (Figure Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3857 / 3861

页数：5

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