Exact ground state properties of the classical Heisenberg model for giant magnetic molecules

被引:61
作者
Axenovich, M [1 ]
Luban, M
机构
[1] Iowa State Univ Sci & Technol, Ames Lab, Ames, IA 50011 USA
[2] Iowa State Univ Sci & Technol, Dept Math, Ames, IA 50011 USA
[3] Iowa State Univ Sci & Technol, Dept Phys & Astron, Ames, IA 50011 USA
来源
PHYSICAL REVIEW B | 2001年 / 63卷 / 10期
关键词
D O I
10.1103/PhysRevB.63.100407
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We find the exact ground state energy and magnetic moment for an arbitrary magnetic field H of the classical Heisenberg model of spins on the vertices of an icosidodecahedron. This model provides an accurate description of the magnetic properties of the giant paramagnetic molecule {Mo72Fe30} in which 30 Fe3+ ions are coupled via antiferromagnetic exchange. The strong frustration of the magnetic interaction in the molecule is relaxed when the angle between nearest-neighbor spins is 120 degrees. We predict that the magnetic moment is linear with H until saturating at a critical field H-c, and this is consistent with the results of a recent experiment at 0.46 K. We derive our results using a graph-theoretical construction and a special property, three-colorability, of the icosidodecahedron. We also consider spins on the vertices of an octahedron, icosahedron, and dodecahedron.
引用
收藏
页数:4
相关论文
共 15 条
[1]   ORDERING AND ANTIFERROMAGNETISM IN FERRITES [J].
ANDERSON, PW .
PHYSICAL REVIEW, 1956, 102 (04) :1008-1013
[2]  
[Anonymous], UNPUB
[3]   Equation of state and spin-correlation functions of ultrasmall classical Heisenberg magnets [J].
Ciftja, O ;
Luban, M ;
Auslender, M ;
Luscombe, JH .
PHYSICAL REVIEW B, 1999, 60 (14) :10122-10133
[4]  
Coxeter H. S. M., 1973, REGULAR POLYTOPES
[5]   MAGNETISM IN 1-DIMENSIONAL SYSTEMS - HEISENBERG MODEL FOR INFINITE SPIN [J].
FISHER, ME .
AMERICAN JOURNAL OF PHYSICS, 1964, 32 (05) :343-+
[6]   LARGE CLUSTERS OF METAL-IONS - THE TRANSITION FROM MOLECULAR TO BULK MAGNETS [J].
GATTESCHI, D ;
CANESCHI, A ;
PARDI, L ;
SESSOLI, R .
SCIENCE, 1994, 265 (5175) :1054-1058
[7]   MOLECULAR MAGNETISM - A BASIS FOR NEW MATERIALS [J].
GATTESCHI, D .
ADVANCED MATERIALS, 1994, 6 (09) :635-645
[8]  
LUBAN M, UNPUB
[9]   Classical Heisenberg model of magnetic molecular rings clusters: Accurate approximants for correlation functions and susceptibility [J].
Luscombe, JH ;
Luban, M ;
Borsa, F .
JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (17) :7266-7273
[10]   Low-temperature properties of classical geometrically frustrated antiferromagnets [J].
Moessner, R ;
Chalker, JT .
PHYSICAL REVIEW B, 1998, 58 (18) :12049-12062