Turbulent aggregation of alumina in water and n-heptane

被引:23
作者
Saint-Raymond, H [1 ]
Gruy, F [1 ]
Cournil, M [1 ]
机构
[1] Ecole Mines St Etienne, F-42023 St Etienne 2, France
关键词
aggregation; fractal; turbulence; breakage; turbidimetry; light scattering;
D O I
10.1006/jcis.1998.5436
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Aggregation of alumina powder in water and n-heptane is followed by turbidimetry in situ. The experiments are carried out under turbulent conditions. They are discussed in the framework of a model which takes into account the hydrodynamic and physicochemical aspects of aggregation. A good agreement between measured and predicted turbidity is found provided the aggregates are considered as noncompact and liable to undergo fragmentation. Recent models of aggregation and fragmentation of fractal-like clusters are successfully tested. The aggregate morphology seems to depend on the nature of the liquid medium, however, not on the stirring rate. (C) 1998 Academic Press.
引用
收藏
页码:238 / 250
页数:13
相关论文
共 46 条
[21]   Spectroturbidimetry of fractal clusters: Test of density correlation function cutoff [J].
Khlebtsov, NG .
APPLIED OPTICS, 1996, 35 (21) :4261-4270
[22]   THE LOCAL-STRUCTURE OF TURBULENCE IN INCOMPRESSIBLE VISCOUS-FLUID FOR VERY LARGE REYNOLDS-NUMBERS [J].
KOLMOGOROV, AN .
PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1991, 434 (1890) :9-13
[23]  
Kusters K. A., 1991, THESIS EINDHOVEN U T
[24]   Aggregation kinetics of small particles in agitated vessels [J].
Kusters, KA ;
Wijers, JG ;
Thoenes, D .
CHEMICAL ENGINEERING SCIENCE, 1997, 52 (01) :107-121
[25]  
Landau L., 1986, FLUID MECH-SOV RES
[26]  
LESIEUR M, 1994, TURBULENCE
[27]  
Levich V.G., 1962, Physicochemical Hydrodynamics
[28]   LIGHT SCATTERING BY 2 SPHERICAL RAYLEIGH PARTICLES OVER ALL ORIENTATIONS [J].
LIPS, A ;
LEVINE, S .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1970, 33 (03) :455-&
[29]   Theoretical model for drop and bubble breakup in turbulent dispersions [J].
Luo, H ;
Svendsen, HF .
AICHE JOURNAL, 1996, 42 (05) :1225-1233
[30]   SHEAR-INDUCED AGGREGATION AND BREAKUP OF POLYSTYRENE LATEX-PARTICLES [J].
OLES, V .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1992, 154 (02) :351-358