A simple and green approach for preparation of ZnO2 and ZnO under sunlight irradiation

被引:68
作者
Sun, Meng
Hao, Welchang [1 ]
Wang, Chunzhong
Wang, Tianmin
机构
[1] Beijing Univ Aeronaut & Astronaut, Sch Sci, Ctr Mat Phys & Chem, Beijing 100083, Peoples R China
[2] Zhengzhou Univ Light Ind, Dept Technol & Phys, Zhengzhou 450002, Peoples R China
关键词
D O I
10.1016/j.cplett.2007.06.098
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A green approach is developed for sol-gel synthesis of ZnO and ZnO2 through photochemical reaction under sunlight irradiation. The component and structure of the sol and powders are systematically analyzed, and the reaction equations are deduced and the fabrication mechanisms are discussed. It is found that the ZnO2 powder is obtained when sintering temperature is below 200 degrees C, while ZnO powder is obtained as sintering temperature increases from 200 to 800 degrees C. All ZnO and ZnO2 prepared by this method are with crystal structure and high purity. Our fabrication process has low energy consumption and it brings no environment pollution. This simple and green approach is considered of great potential applications in industry. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:342 / 346
页数:5
相关论文
共 19 条
[1]   Infrared dielectric functions and phonon modes of high-quality ZnO films [J].
Ashkenov, N ;
Mbenkum, BN ;
Bundesmann, C ;
Riede, V ;
Lorenz, M ;
Spemann, D ;
Kaidashev, EM ;
Kasic, A ;
Schubert, M ;
Grundmann, M ;
Wagner, G ;
Neumann, H ;
Darakchieva, V ;
Arwin, H ;
Monemar, B .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (01) :126-133
[2]   Hybrid solar cells from regioregular polythiophene and ZnO nanoparticles [J].
Beek, Waldo J. E. ;
Wienk, Martijn M. ;
Janssen, Rene A. J. .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (08) :1112-1116
[3]   Bulk acoustic resonator based on piezoelectric ZnO belts [J].
Buchine, Brent A. ;
Hughes, William L. ;
Degertekin, F. Levent ;
Wang, Zhong L. .
NANO LETTERS, 2006, 6 (06) :1155-1159
[4]  
Cullity B., 1978, ELEMENTS XRAY DIFFRA
[5]   Fully transparent ZnO thin-film transistor produced at room temperature [J].
Fortunato, EMC ;
Barquinha, PMC ;
Pimentel, ACMBG ;
Gonçalves, AMF ;
Marques, AJS ;
Pereira, LMN ;
Martins, RFP .
ADVANCED MATERIALS, 2005, 17 (05) :590-+
[6]  
HAGEL R, 1981, Patent No. 4363679
[7]   Thermally grown ZnO nanorods from Zn ingot [J].
Han, KR ;
Jang, HJ ;
Kim, CS .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2005, 113 (1317) :337-339
[8]   ZnO nanowire growth and devices [J].
Heo, YW ;
Norton, DP ;
Tien, LC ;
Kwon, Y ;
Kang, BS ;
Ren, F ;
Pearton, SJ ;
LaRoche, JR .
MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2004, 47 (1-2) :1-47
[9]   Ionic elastomers based on carboxylated nitrile rubber (XNBR) and zinc peroxide: Influence of carboxylic group content on properties [J].
Ibarra, L ;
Alzorriz, M .
JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 84 (03) :605-615
[10]   Mechanistic approach to the curing of carboxylated nitrile rubber (XNBR) by zinc peroxide/zinc oxide [J].
Ibarra, L ;
Marcos-Fernández, A ;
Alzorriz, M .
POLYMER, 2002, 43 (05) :1649-1655