The physical and electrochemical characterization of vapor phase iodated activated carbons

被引:17
作者
Barpanda, P. [1 ]
Fanchini, G. [1 ]
Amatucci, G. G. [1 ]
机构
[1] State Univ New Jersy, Dept Mat Sci & Engn, Energy Storage Res Grp, N Brunswick, NJ 08902 USA
关键词
activated carbon; iodine; EDLC; non-Faradaic; non-aqueous;
D O I
10.1016/j.electacta.2007.05.051
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
properties of carbons iodated under various conditions were investigated. The iodine incorporation induced marked structural and electrochemical modification of activated carbons. These compounds resulted in a unique combination of high volumetric/gravimetric capacity. Specifically, the incorporation of halide leads to a 200-500% increase in volumetric, capacity of carbon materials. The resulting improvement is brought about through a modification of the non-Faradaic performance and development of a psuedocapacitive reaction at approximately 3.1 V Both of these reactions have contributed to the higher volumetric capacity and are investigated relative to the synthesis conditions of the compound. (c) 2007 Published by Elsevier Ltd.
引用
收藏
页码:7136 / 7147
页数:12
相关论文
共 26 条
[1]   An asymmetric hybrid nonaqueous energy storage cell [J].
Amatucci, GG ;
Badway, F ;
Du Pasquier, A ;
Zheng, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (08) :A930-A939
[2]   Fluoride based electrode materials for advanced energy storage devices [J].
Amatucci, Glenn G. ;
Pereira, Nathalie .
JOURNAL OF FLUORINE CHEMISTRY, 2007, 128 (04) :243-262
[3]   Physical and electrochemical properties of iodine-modified activated carbons [J].
Barpanda, P. ;
Fanchini, G. ;
Amatucci, G. G. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (05) :A467-A476
[4]  
BARPANDA P, 2006, MAT RES S P E, V973
[5]   A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS [J].
BENESI, HA ;
HILDEBRAND, JH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) :2703-2707
[6]   Ultracapacitors: why, how, and where is the technology [J].
Burke, A .
JOURNAL OF POWER SOURCES, 2000, 91 (01) :37-50
[7]  
Conway B. E., 1999, ELECTROCHEMICAL SUPE
[8]   Effect of mechanical grinding on the lithium intercalation process in graphites and soft carbons [J].
Disma, F ;
Aymard, L ;
Dupont, L ;
Tarascon, JM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (12) :3959-3972
[9]   Characteristics and performance of 500 F asymmetric hybrid advanced supercapacitor prototypes [J].
Du Pasquier, A ;
Plitz, I ;
Gural, J ;
Menocal, S ;
Amatucci, G .
JOURNAL OF POWER SOURCES, 2003, 113 (01) :62-71
[10]   Interpretation of Raman spectra of disordered and amorphous carbon [J].
Ferrari, AC ;
Robertson, J .
PHYSICAL REVIEW B, 2000, 61 (20) :14095-14107